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Diacetone acrylamide (DAAM) is a versatile organic compound widely utilized in polymer science, coating technology, and material science. It is a synthetic monomer that has gained significant attention due to its unique chemical properties, such as high reactivity, ability to form diverse polymer structures, and capacity for various functional applications. DAAM plays an important role in enhancing the properties of polymers, coatings, adhesives, and composites.
Diacetone acrylamide is an acrylamide derivative, where the acrylamide group is substituted by an acetone moiety at the nitrogen position. The chemical formula of DAAM is C₆H₁₁NO₂, and its molecular weight is approximately 129.17 g/mol.
The structure of DAAM consists of:
CAS No :2873-97-4
TSCA :2873-97-4
EINECS :220-713-2
ENCS :2-1024
Features
The presence of the acrylamide functional group allows DAAM to polymerize in a manner similar to other acrylamide-based monomers, while the diacetone structure provides a steric hindrance that influences its reactivity and physical properties. The acetone group also makes the compound more soluble in organic solvents.
The synthesis of DAAM involves a two-step process:
Acylation of acrylamide: This first step involves reacting acrylamide with acetone in the presence of an acid or base catalyst. The acetone reacts with the nitrogen atom of the acrylamide to form the diacetone derivative.
Purification: Once the reaction is complete, the product is typically purified through distillation or crystallization techniques to isolate the DAAM monomer in its pure form.
The reaction can be described as:
The synthesis of DAAM is relatively straightforward, but precise control of reaction conditions (e.g., temperature, reaction time, solvent choice) is required to achieve high yields and purity.
The most significant feature of DAAM is its ability to undergo free radical polymerization. The acrylamide group in DAAM can participate in addition polymerization reactions, allowing DAAM to link with other monomers or itself to form long polymer chains. This makes DAAM a useful monomer in the production of polymers with varied properties.
The polymerization of DAAM can proceed through:
Free radical initiators (e.g., AIBN, BPO) or UV light are often used to initiate the polymerization process. The resulting DAAM-based polymers can have a wide range of properties depending on the degree of polymerization, the presence of crosslinking agents, and the type of co-monomers used.
Properties
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Copolymerization
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DAAM is widely used in the formulation of coatings and paints due to its ability to create polymers with strong adhesion, flexibility, and resistance to environmental factors. The resulting polymer films exhibit improved performance compared to traditional acrylic or polyester-based coatings.
Some specific applications include:
DAAM is used in the development of superabsorbent polymers (SAPs), which are materials capable of absorbing large amounts of water or other liquids. These materials are often used in applications such as:
Due to its biocompatibility and versatility, DAAM is also explored in the medical and biomedical fields. For instance:
Hydrogels made from DAAM are used in various applications due to their high water retention properties. These hydrogels can be used in:
DAAM is also used in the preparation of nanocomposites and advanced polymer-based materials. For example, DAAM can be polymerized with nanoparticles to form hybrid materials with enhanced mechanical, electrical, or thermal properties. These materials can be used in various industries, including:
In the textile industry, DAAM is utilized to produce fabrics with enhanced durability and flexibility. For instance, functional coatings based on DAAM can be applied to textiles to make them more resistant to water, stains, and UV radiation. Similarly, DAAM can be used in the production of printing inks, where its ability to form high-quality films helps in achieving better print clarity and durability.
20kg cardboard boxWe take “customer-friendly, quality-oriented, integrative, innovative” as objectives. “Truth and honesty” is our administration ideal for China Supplier Adipic Dihydrazide Adh (curing agent), With advantage of industry management, the firm has generally been committed to supporting prospects to become the industry leader in their respective industries.
China Supplier Adipic Dihydrazide and Adh, Wide selection and fast delivery for you! Our philosophy: Good quality, great service, keep improving. We are looking forward that more and more oversea friends join in our family for further development near the future!